dc.creator | Slack, John James | |
dc.date.accessioned | 2020-08-21T20:57:19Z | |
dc.date.available | 2019-01-28 | |
dc.date.issued | 2019-01-28 | |
dc.identifier.uri | https://etd.library.vanderbilt.edu/etd-01242019-221422 | |
dc.identifier.uri | http://hdl.handle.net/1803/10479 | |
dc.description.abstract | Fuel cells offer high energy-density and high power-density as sustainable, portable energy conversion devices. Obstacles to mass-market adoption of this technology include insufficient durability (power density retention after stress tests), low performance at realistic operating conditions (e.g. ≤40% relative humidity), and the high cost of materials (e.g. platinum catalyst). Through electrospinning and innovative catalyst ink preparation, this work addresses each obstacle by (1) improving durability of platinum-free electrodes using a Nafion and polyvinylidene fluoride (PVDF) binder, (2) increasing power and durability of PtCo/C as a cathode catalyst in membrane electrode assemblies (MEAs) with a Nafion/PAA binder, (3) analyzing MEAs with Pt/C and Nafion/PVDF at Oak Ridge National Laboratory (4) using sol-gel chemistry before, during, and after the electrospinning process to create a hybrid organic/inorganic network binder (5) developing a catalyst ink which allowed for the removal of the carrier polymer resulting in a high performance neat Nafion nanofiber electrode MEA. | |
dc.format.mimetype | application/pdf | |
dc.subject | Nanofibers | |
dc.subject | Electrospinning | |
dc.subject | Fuel Cells | |
dc.subject | Energy | |
dc.subject | Hydrogen | |
dc.title | Next Generation Electrospun Nanofiber Electrodes for Hydrogen/Air Fuel Cells | |
dc.type | dissertation | |
dc.contributor.committeeMember | Kane Jennings | |
dc.contributor.committeeMember | Rizia Bardhan | |
dc.contributor.committeeMember | Janet Macdonald | |
dc.type.material | text | |
thesis.degree.name | PHD | |
thesis.degree.level | dissertation | |
thesis.degree.discipline | Chemical Engineering | |
thesis.degree.grantor | Vanderbilt University | |
local.embargo.terms | 2019-01-28 | |
local.embargo.lift | 2019-01-28 | |
dc.contributor.committeeChair | Peter Pintauro | |