Show simple item record

Interlaced crystals having a perfect Bravais lattice and complex chemical order revealed by real-space crystallography

dc.contributor.authorShen, Xiao
dc.contributor.authorHerna´ndez-Pagan, Emil A
dc.contributor.authorZhou, Wu
dc.contributor.authorPuzyrev, Yevgeniy S.
dc.contributor.authorIdrobo, Juan-Carlos
dc.contributor.authorMacdonald, Janet E.
dc.contributor.authorPennycook, Stephen J.
dc.contributor.authorPantelides, Sokrates T.
dc.date.accessioned2018-04-02T15:48:49Z
dc.date.available2018-04-02T15:48:49Z
dc.date.issued2014-11-14
dc.identifier.issn10.1038/ncomms6431
dc.identifier.urihttp://hdl.handle.net/1803/8802
dc.description.abstractThe search for optimal thermoelectric materials aims for structures in which the crystalline order is disrupted to lower the thermal conductivity without degradation of the electron conductivity. Here we report the synthesis and characterisation of ternary nanoparticles (two cations and one anion) that exhibit a new form of crystalline order: an uninterrupted, perfect, global Bravais lattice, in which the two cations exhibit a wide array of distinct ordering patterns within the cation sublattice, forming interlaced domains and phases. Partitioning into domains and phases is not unique; the corresponding boundaries have no structural defects or strain and entail no energy cost. We call this form of crystalline order ‘interlaced crystals’ and present the example of hexagonal CuInS2. Interlacing is possible in multi-cation tetrahedrally bonded compound with an average of two electrons per bond. Interlacing has minimal effect on electronic properties, but should strongly reduce phonon transport, making interlaced crystals attractive for thermoelectric applications.en_US
dc.subjectInterlaced crystals; Bravais lattice; real-space crystallographyen_US
dc.subject.lcshchemistryen_US
dc.titleInterlaced crystals having a perfect Bravais lattice and complex chemical order revealed by real-space crystallographyen_US
dc.typeArticleen_US


Files in this item

Icon

This item appears in the following Collection(s)

Show simple item record